1-Chloro-3-Ethenylbenzene
Linshang Chemical
HS Code |
987442 |
Chemical Formula | C8H7Cl |
Molecular Weight | 138.594 g/mol |
Appearance | Colorless to pale - yellow liquid |
Boiling Point | 201 - 203 °C |
Melting Point | -27 °C |
Density | 1.088 g/mL at 25 °C |
Solubility In Water | Insoluble |
Solubility In Organic Solvents | Soluble in many organic solvents like ethanol, ether |
Vapor Pressure | 0.23 mmHg at 25 °C |
Flash Point | 78 °C |
Odor | Pungent aromatic odor |
As an accredited 1-Chloro-3-Ethenylbenzene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
Packing | 1 - chloro - 3 - ethenylbenzene: Packed in 5 - liter containers for safe storage and transport. |
Storage | 1 - Chloro - 3 - ethenylbenzene should be stored in a cool, well - ventilated area away from heat, sparks, and open flames as it is flammable. Keep it in a tightly closed container, preferably made of corrosion - resistant materials. Store it separately from oxidizing agents and reactive chemicals to prevent potential hazardous reactions. |
Shipping | 1 - Chloro - 3 - ethenylbenzene should be shipped in tightly sealed, corrosion - resistant containers. It must be labeled as a hazardous chemical. Shipments should comply with all relevant regulations to ensure safe transport. |
Competitive 1-Chloro-3-Ethenylbenzene prices that fit your budget—flexible terms and customized quotes for every order.
For samples, pricing, or more information, please call us at +8615365006308 or mail to info@alchemist-chem.com.
We will respond to you as soon as possible.
Tel: +8615365006308
Email: info@alchemist-chem.com


As a leading 1-Chloro-3-Ethenylbenzene supplier, we deliver high-quality products across diverse grades to meet evolving needs, empowering global customers with safe, efficient, and compliant chemical solutions.
Let me talk about its halogenated hydrocarbon properties first. Because it contains chlorine atoms, chlorine atoms are highly active. When encountering nucleophiles, chlorine atoms are easily replaced. If co-heated with sodium alcohol, chlorine will be replaced by alkoxy groups to form corresponding ether compounds. In this reaction, the nucleophilic reagent alkoxy anion attacks the carbon atom connected to the chlorine atom, and the chlorine leaves with a pair of electrons to complete the replacement.
Let's look at the properties of its carbon-carbon double bond. Carbon-carbon double bonds are rich in electrons and have high reactivity. An addition reaction can occur, such as when it meets bromine water, the double bond is opened, and the bromine atom is added to the two carbon atoms respectively, so that the bromine water fades. This is a common method for identifying carbon-carbon double bonds. Under the action of a catalyst with hydrogen, a hydrogenation reaction can occur to form a saturated hydrocarbon derivative.
In addition, the benzene ring of 1-chloro-3-vinylbenzene also has its own characteristics. The benzene ring has a conjugated system and is relatively stable, but it can also undergo a substitution reaction. Due to the influence of chlorine atoms and vinyl groups on the electron cloud distribution of the benzene ring, some positions of the benzene ring are more easily replaced. For example, under certain conditions, a nitrification reaction can occur, and a nitro group replaces
Furthermore, 1-chloro-3-vinylbenzene can also undergo polymerization. Carbon-carbon double bonds can be connected to each other under the action of initiators to form polymer, which is of great application value in the field of material synthesis.
In summary, 1-chloro-3-vinylbenzene has rich chemical properties and has important applications in many fields such as organic synthesis.
Looking at its properties, under room temperature and pressure, 1-chloro-3-vinylbenzene is a colorless to light yellow liquid, clear and transparent, shining with light. Its smell is specific and fragrant, but it is different from the common fragrance. If you smell it, you can feel its special smell. This smell can be used as a basis for identification in specific environments.
When it comes to melting point, it is about -48 ° C. When the ambient temperature drops to this temperature, the substance gradually solidifies from a liquid state, the molecular arrangement changes from disorder to order, and the body state changes from a flowing liquefaction to a fixed solid. Its boiling point is in the range of 197-199 ° C. If it is heated and the temperature rises to this temperature, the thermal motion of the molecules intensifies, breaking free from each other's bondage, and changing from a liquid state to a gaseous state to escape.
The density of 1-chloro-3-vinylbenzene is about 1.079 g/mL. It is heavier than water. If it is mixed with water, it will sink to the bottom of the water. The two are distinct. Its solubility also has characteristics. It is slightly soluble in water, and the hydrogen bonds between water molecules are tight. The molecules of this substance interact weakly with it, so it is difficult to dissolve. However, organic solvents, such as ethanol, ether, benzene, etc., are miscible, because organic solvents are similar in structure to it, "similar and soluble", and can be evenly dispersed between molecules.
In addition, the vapor pressure of 1-chloro-3-vinylbenzene has its fixed value at a specific temperature. The vapor pressure reflects the difficulty of volatilization. This substance has a certain volatility at room temperature. The vapor is scattered in the surrounding space. It is necessary to pay attention to its concentration in the air to prevent safety. Its refractive index is also a specific number. When light passes through, the optical path is deflected due to the influence of the internal structure of the substance. This property is quite valuable in analysis and identification.
First, in the field of synthetic materials, this substance can be used as a monomer for the preparation of special polymers. Through polymerization, it can be copolymerized with other monomers to form polymer materials with unique properties. For example, by copolymerizing with some olefin monomers, the obtained polymer can optimize its mechanical properties and heat resistance. It is very useful in industries that require strict material properties such as aerospace and automobile manufacturing. The presence of chlorine atoms and vinyl groups in its structure endows the polymer with special chemical activity and physical properties, which can enhance the stability and durability of the material.
Second, in the field of organic synthesis, 1-chloro-3-vinylbenzene is an important intermediate. Through various chemical reactions, such as nucleophilic substitution, addition reaction, etc., other functional groups can be introduced to synthesize a series of complex organic compounds. For example, nucleophilic substitution reactions can occur with compounds containing active hydrogen, new carbon-carbon bonds or carbon-heteroatomic bonds can be formed, and biologically active pharmaceutical intermediates can be synthesized, providing key raw materials for pharmaceutical research and development.
Third, in the paint and adhesive industries, it is also indispensable. Because of its reactivity, it can participate in the cross-linking and curing process of coatings and adhesives, and improve the performance of coatings and adhesives. It can enhance the adhesion, hardness and wear resistance of coatings, making coatings more resistant to environmental erosion; in adhesives, it can improve the bonding strength and heat resistance, and broaden its application range. It can be used for bonding of different materials such as metals and plastics.
Fourth, in the field of electronic materials, after specific chemical modification and processing, 1-chloro-3-vinylbenzene can be used to prepare electronic packaging materials, printed circuit board substrates, etc. Its chemical structure can endow materials with good electrical insulation properties and thermal stability, meeting the high performance requirements of electronic equipment and ensuring the stable operation of electronic components.
First, m-chlorotoluene is used as the starting material, and the goal can be achieved by halogenation and elimination reactions. First, m-chlorotoluene is subjected to side chain halogenation reaction with halogens (such as bromine) under the action of light or initiator to generate m-chlorobenzyl halogen derivatives. In this reaction, light or initiator prompts the generation of halogen free radicals, which are substituted with hydrogen atoms on the methyl group of the side chain of toluene. Subsequently, the halogen is eliminated under the action of a strong base (such as potassium hydroxide alcohol solution). The strong base captures the hydrogen atom on the adjacent carbon atom of the halogen atom, and the halogen atom leaves with a pair of electrons to form a carbon-carbon double bond, thereby obtaining 1-chloro-3-vinylbenzene.
Second, using m-chlorobenzaldehyde as a raw material, it can be obtained through a multi-step reaction. First, m-chlorobenzaldehyde is reacted with phosphine-ylide reagent (e.g. prepared from triphenylphosphine and haloalkane). Nucleophilic addition occurs between the carbon anion and the aldehyde group in the phosphine Yelide reagent, and the subsequent intermediate forms eliminates triphenylphosphine oxide to form a carbon-carbon double bond, resulting in 1-chloro-3-vinylbenzene. This reaction condition is mild and the yield is usually high. It is a common method for constructing carbon-carbon double bonds.
Third, m-chloroaniline is synthesized by diazotization and vinylation with m-chloroaniline as the starting material. First, m-chloroaniline is diazotized with sodium nitrite at low temperature and in the presence of strong acids (such as hydrochloric acid) to generate diazonium salts. Diazonium salts are active in nature. Under the catalysis of appropriate copper salts (such as cuprous chloride), they react with vinylating reagents (such as vinyl borate). The diazonium groups are replaced by vinyl groups, and finally 1-chloro-3-vinylbenzene is formed. This process step is relatively complicated, but it can be an effective strategy for specific raw material sources or special requirements for product purity.
In the environment, 1-chloro-3-vinylbenzene may be quite harmful. Its chemical properties make it difficult to decompose in the natural environment and can remain for a long time. If released into the atmosphere, it can interact with light, oxygen, etc., participate in complex photochemical reactions, or cause an increase in atmospheric pollutants, affecting air quality, damaging the ozone layer, and then disturbing the global climate. If it enters the water body, it will sink to the bottom due to its hydrophobicity or attached to suspended particles, posing a threat to aquatic ecosystems. It can cause poisoning to aquatic organisms, interfere with their physiological functions, affect reproduction, growth, and even cause population loss, breaking the ecological balance.
As for the human body, 1-chloro-3-vinylbenzene also has a latent risk. It can accumulate in the body through respiration, skin contact or dietary intake. It may be a carcinogen, long-term exposure increases the risk of cancer, especially the liver, kidneys and other important organs. And can irritate the skin, eyes and respiratory tract, causing skin allergies, redness and swelling, eye tingling, tears, respiratory discomfort, cough and other symptoms. It may also affect the nervous system, causing dizziness, headache, fatigue, memory loss, etc., especially for developing fetuses and children, and can cause developmental abnormalities.
Therefore, 1-chloro-3-vinylbenzene should be strictly regulated to prevent its wanton discharge to protect the environment and human health.
In this compound, the bromine atom is active and can participate in many nucleophilic substitution reactions. For example, in a strong alkali environment, bromine ions can be replaced by hydroxyl groups, alkoxy groups and other nucleophilic reagents to form corresponding alcohols or ethers. For example, 1-bromo-3-isopropylbenzene is treated with an aqueous solution of sodium hydroxide. After nucleophilic substitution, the bromine atom is replaced by a hydroxyl group to obtain 3-isopropylphenol.
Its phenyl ring is aromatic due to its large π bond, and it is prone to electrophilic substitution. If it is co-heated with concentrated nitric acid and concentrated sulfuric acid mixed acid, the hydrogen atom on the benzene ring will be replaced by nitro, and the main product of o-nitro or p-nitro substitution will be formed. Because isopropyl is the o-and para-site locator, it guides the nitro group into the o-and para-site of the benzene ring.
isopropyl also affects the properties of the compound. Isopropyl has a certain electron-induced effect, which increases the electron cloud density of the benzene ring and enhances the activity of the electrophilic substitution reaction of the benzene ring. At the same time, the isopropyl group can undergo oxidation reaction. Under the action of a specific strong oxidant, the carbon-hydrogen bond on the isopropyl group can be oxidi
1-bromo-3-isopropylbenzene is widely used in the field of organic synthesis. It can be used as a key intermediate to construct complex organic molecular structures through various reactions, providing an important foundation for the research and practical application of organic synthesis chemistry.
First, in the field of organic synthesis, its role is significant. Deuterium has unique nuclear properties and is often used as a tracer atom. Introducing it into the structure of 3-isopropylbenzene can clarify the mechanism and path of chemical reactions by tracking the whereabouts of deuterium. This provides key information for chemists in exploring the process of complex organic reactions and analyzing reaction intermediates, helping to precisely control organic synthesis reactions and improve the yield and purity of target products.
Second, in the field of materials science, it also has extraordinary performance. 3-Isopropylbenzene can be used as a raw material to prepare materials with special properties after specific chemical modification and deuteration. For example, in the synthesis of polymer materials, it can be used as a monomer or additive to change the physical and chemical properties of the material. Due to the quality difference of deuterium, it can affect the crystallinity and glass transition temperature of the material, endowing the material with properties such as higher stability and heat resistance, and meet the strict requirements of high-end fields such as aerospace and electronic devices.
Third, in the field of pharmaceutical research and development, it also plays an important role. Deuterated 3-Isopropylbenzene derivatives may have unique pharmacokinetic and pharmacodynamic properties. After some drug molecules are introduced into deuterium atoms, their metabolic stability is enhanced, which can prolong the action time of the drug in the body, reduce the frequency and dosage of the drug, reduce the side effects of the drug, open up new paths for the development of new drugs, and improve the therapeutic effect and safety of the drug.
Take isopropylbenzene first, which is the starting material. Put the isopropylbenzene in an appropriate reaction vessel, introduce bromine (Br -2) as a catalyst, and carry out bromination reaction. In this reaction, because the isopropyl group is the ortho and para-site group, based on the positioning effect, the bromine atom will mainly replace the hydrogen atom of the isopropyl para-site on the phenyl ring, thereby generating 1-bromo-3-isopropylbenzene. When reacting, it is necessary to pay attention to the control of the reaction temperature. It should not be too high or too low. If it is too high, side reactions will increase, and if it is too low, the reaction rate will be slow. Generally speaking, it is appropriate to control the reaction temperature near room temperature. And during the reaction process, it is necessary to ensure that the reactants are fully mixed, which can be achieved by stirring. This is a more conventional synthesis path. With the characteristics of the positioning group, the target product 1-bromo-3-isopropylbenzene can be obtained more efficiently. However, it should be noted that after the reaction, the product may contain impurities, such as unreacted raw materials, side reaction products, etc. Therefore, it needs to be separated and purified by methods such as distillation and recrystallization to obtain pure 1-bromo-3-isopropylbenzene.
> > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > >
> >
> > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > > >
As for trimethoxybenzyl, some of which have a certain biological activity. If its phase is released into the environment, it may affect the balance of the microbial community. Microorganisms are very important for biological circulation, such as soil microbial decomposition, separation, etc. Trimethoxybenzyl compounds or modified microorganisms are important for soil fertility and biological function. It or aquatic organisms have specific toxicity, breaking the determination of aquatic systems. Aquatic organisms are sensitive to this substance, and often cause death, which affects the integrity of aquatic food.
Therefore, the compounds involved in trimethoxybenzyl may cause general environmental effects in different ways and in different ways, such as environmental balance and biological health. It is necessary to be careful to prevent and control their release and accumulation in the environment.
First heavy fire and source. Because of its flammability, in case of open fire, high temperature or oxidation, there is a risk of ignition explosion. It should not exceed 37 ° C. Keep the container tight.
Furthermore, store it in parts such as oxidation, acid, and oil, and do not mix. There are no suitable materials to contain leaks.
It is also necessary to pay attention to the emergency management of fire equipment and leaks. It is best to leave it in the morning and evening in summer. The troughs (tanks) used in the warehouse should be grounded, and the troughs can be baffled to produce low vibration. It is forbidden to mix and mix oxidizing, acid, oil, edible chemicals, etc. On the way, it is necessary to prevent exposure, rain, and height. Stop-over for fire, gas, and high temperature. The exhaust pipes of the warehouse must be equipped with fire-blocking devices, and it is forbidden to use easy-to-start sparks and tools for unloading. Roads should be run according to the designated route, and do not stop in residential areas and densely populated areas. Roads should be prohibited from slipping away. This kind of equipment must be followed to ensure the safety of 1 + - 3 - propyl phenyl ether.

Scan to WhatsApp