Benzene, 1-Chloro-4-Ethenyl-
Linshang Chemical
HS Code |
259106 |
Chemical Formula | C8H7Cl |
Molar Mass | 138.594 g/mol |
Appearance | Colorless to pale - yellow liquid |
Odor | Characteristic aromatic odor |
Density | 1.063 g/mL at 25 °C |
Boiling Point | 195 - 197 °C |
Melting Point | -23 °C |
Solubility In Water | Insoluble |
Solubility In Organic Solvents | Soluble in many organic solvents like ethanol, ether |
Flash Point | 72 °C |
Vapor Pressure | 0.17 mmHg at 25 °C |
Stability | Stable under normal conditions, but may polymerize upon exposure to heat, light or catalysts |
As an accredited Benzene, 1-Chloro-4-Ethenyl- factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
Packing | 500g of 1 - chloro - 4 - ethenyl - benzene packaged in a sealed, corrosion - resistant bottle. |
Storage | Store "Benzene, 1 - chloro - 4 - ethenyl -" (4 - chloro - 1 - vinylbenzene) in a cool, well - ventilated area, away from heat, sparks, and open flames due to its flammability. Keep it in a tightly sealed container made of materials resistant to corrosion. Separate it from oxidizing agents and incompatible substances to prevent dangerous reactions. |
Shipping | 1 - Chloro - 4 - ethenyl - benzene is shipped in accordance with strict hazardous material regulations. It's typically transported in specialized containers, ensuring leak - proof and secure transit to prevent environmental and safety risks. |
Competitive Benzene, 1-Chloro-4-Ethenyl- prices that fit your budget—flexible terms and customized quotes for every order.
For samples, pricing, or more information, please call us at +8615365006308 or mail to info@alchemist-chem.com.
We will respond to you as soon as possible.
Tel: +8615365006308
Email: info@alchemist-chem.com


As a leading Benzene, 1-Chloro-4-Ethenyl- supplier, we deliver high-quality products across diverse grades to meet evolving needs, empowering global customers with safe, efficient, and compliant chemical solutions.
First, in the field of material synthesis, p-chlorobenzene can be used as a monomer and polymerized to form chlorine-containing polymers. This type of polymer has unique properties, such as high thermal stability, chemical stability and flame retardancy. For example, in the preparation of special engineering plastics, the copolymerization of p-chlorobenzene with other monomers can optimize material properties and improve its performance in high temperature and chemical corrosion environments. It is widely used in high-end fields such as aerospace, electronics and electrical appliances.
Second, in the field of organic synthesis chemistry, p-chlorobenzene, as a key intermediate, participates in the synthesis of many organic compounds. Due to the presence of styrene rings and vinyl groups, a variety of chemical reactions can occur, such as addition, substitution, etc. With the help of these reactions, chemists can build organic molecules with diverse structures for the preparation of drugs, pesticides, and fine chemicals. For example, in the development of some new drugs, p-chlorobenzene is converted into molecular structures with specific biological activities through a series of reactions, providing the basis for drug innovation.
Third, p-chlorobenzene can also be used to produce coatings and adhesives. In coatings, its polymers can enhance the hardness, wear resistance and chemical resistance of the coating, making the coating suitable for harsh environments. In terms of adhesives, adhesives containing p-chlorostyrene can provide stronger adhesion and stability, and are used in automotive manufacturing, construction, and other industries.
- ** Properties **: Under normal conditions, p-chlorobenzene is a colorless to light yellow liquid with a pure and translucent appearance and no obvious impurities. This property makes it convenient to apply in many industrial production and experimental scenarios with strict requirements on appearance.
- ** Odor **: It has a unique aromatic smell. Although the smell is not extremely strong and pungent, its uniqueness can be used as one of the basis for identifying the substance. During production, storage and use, operators can use this smell to initially detect whether there are abnormal conditions such as leakage.
- ** Boiling Point **: The boiling point is about 197 - 200 ° C. A higher boiling point means that a higher temperature is required to transform it from liquid to gaseous state. This characteristic plays a key role in setting process conditions in chemical operations such as distillation and separation involving the gasification and condensation of substances. For example, when separating p-chlorostyrene and other mixtures with large boiling points, the boiling point characteristics can be used to precisely control the temperature and achieve efficient separation.
- ** Melting Point **: The melting point is about -22 ° C. A lower melting point indicates that the substance can be converted from solid to liquid at relatively low temperatures. When storing and transporting in a low temperature environment, this characteristic needs to be considered to prevent the change of the material state from affecting its quality or packaging.
- ** Density **: The density is about 1.06 g/cm ³, which is slightly higher than the density of water. This property is significant in systems involving liquid-liquid separation or coexistence with water. For example, in some reaction systems, if p-chlorostyrene is generated to be immiscible with water, it will appear stratification due to the density difference, so that preliminary separation can be achieved by operations such as liquid separation.
- ** Solubility **: It is difficult to dissolve in water, but it is soluble in most organic solvents, such as ethanol, ether, acetone, etc. This solubility characteristic determines its application in organic synthesis. In organic reactions, its solubility in organic solvents is often used to select a suitable solvent to build a reaction environment and promote the reaction. At the same time, when treating wastewater containing p-chlorostyrene, due to its insoluble nature in water, special treatment processes such as extraction are required to separate it from the water.
p-chlorostyrene has the dual characteristics of olefins and halogenated aromatics. In terms of olefin properties, carbon-containing double bonds are the check point for its active reaction. Addition reactions can occur. In case of bromine water, the double bonds are opened, and the bromine atoms are added to the two carbon atoms to form dibromide, which is like "double dragons play beads, beads fall double forks". Under suitable catalysts and temperatures, it can be added with hydrogen to turn double bonds into single bonds, resulting in saturated halogenated aromatics, similar to "double bond unloading, stable transformation".
And because it contains halogen atoms, it has the properties of halogenated aromatics. In strong alkali alcohol solutions, chlorine atoms can be replaced by hydroxyl groups, and after elimination reactions, p-vinylphenol is formed, which can be described as "chlorine separates from hydroxyl groups and rearranges the structure". In the nucleophilic substitution reaction, chlorine atoms are also easily replaced by nucleophilic reagents, such as cyano, amino groups, etc., to construct new compounds, just like "the abdication of the old master and the enthronement of the new master".
In addition, p-chlorostyrene is relatively stable due to its conjugated system and can participate in the polymerization reaction. Under the action of the initiator, the carbon-carbon double bonds are connected one by one to polymerize into high molecular polymers, which are widely used and have many achievements in the field of materials, like "monomers holding hands and converging into forests". Its chemical properties are diverse, providing many possibilities for organic synthesis and material preparation, and are of great significance in chemical research and industrial production.
Ancient preparation method, or there are various paths. First, p-chlorotoluene can be used as the starting material. First, p-chlorotoluene and N-bromosuccinimide (NBS) are used in the presence of an initiator such as benzoyl peroxide to carry out a free radical substitution reaction. This reaction is the introduction of bromine atoms at the benzyl position of toluene to generate p-chlorobenzyl bromide. P-chlorobenzyl bromide is then co-heated with a strong base such as sodium hydroxide alcohol solution. After the elimination reaction, hydrogen bromide is removed to obtain p-chlorobenzene. The chemical reaction formula is as follows:
p-chlorotoluene + NBS (initiator) → p-chlorobenzyl bromide
p-chlorobenzyl bromide + NaOH (alcohol solution) → p-chlorobenzene + NaBr + H2O O
Second, p-chlorobenzaldehyde can also be prepared from p-chlorobenzaldehyde. First, p-chlorobenzaldehyde is reacted with phosphine Yelide reagent, that is, Wittig reagent. Wittig reagent is prepared by reacting triphenylphosphine with halogenated hydrocarbons and then reacting with strong bases. P-chlorobenzaldehyde reacts with Wittig reagent. Through the Wittig reaction mechanism, the carbon anion of the aldehyde group and the phosphine Yelide reagent undergoes nucleophilic addition, and then triphenylphosphine oxide is eliminated, thereby generating p-chlorophenylvinyl. The reaction conditions are mild and the product selectivity is high. The reaction formula is roughly as follows:
p-chlorobenzaldehyde + Wittig reagent → p-chlorobenzene + triphenylphosphine oxide
or p-chlorobenzene is used as the starting material, which is first reduced to p-chlorobenzene ethanol, and then catalyzed by concentrated sulfuric acid for dehydration. However, this path step is slightly complicated, and when concentrated sulfuric acid is dehydrated, side reactions may occur, so it is not a commonly used method.
The methods for preparing p-chlorostyrene have their own advantages and disadvantages. It is necessary to choose the appropriate method according to the actual conditions, such as the availability of raw materials, the level of cost, and the purity of the product.
And 1-chloro-4-vinylbenzene is chemically active, or reacts with other substances in the environment to generate new pollutants, increasing environmental complexity and harm. In the soil, it may affect the structure and function of the soil microbial community, inhibit the growth of beneficial microorganisms in the soil, destroy the soil ecological balance, cause soil fertility to decline, and affect vegetation growth.
In addition, if it is not properly managed and leaks during production, storage and transportation, it will quickly pollute the surrounding environment and cause local ecological disasters. Therefore, this material should be strictly controlled to reduce its negative impact on the environment from the source to ensure the safety of the ecological environment.

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